
In this course, we will see how quantum mechanics describes electrons using wavefunctions, quantum numbers, and atomic orbitals. These ideas explain how electrons are arranged in atoms, the shapes and energies of orbitals, and why elements have different chemical properties.
The Heisenberg uncertainty principle, is a fundamental concept in quantum mechanics . It states:
it is impossible to precisely determine both the position and momentum (or velocity) of a particle simultaneously. The more accurately one of these properties is measured, the less accurately the other can be determined.
The Schrödinger Equation, developed by Erwin Schrödinger in 1926, is a fundamental equation in quantum mechanics that describes the behavior of a particle at the quantum level.
This equation incorporates the mass (m), energy (E), potential energy (V) and the wave function (ψ) for submicroscopic particles, such as electrons.
The mathematical solution of the Schrödinger equation for the hydrogen atom provides a detailed understanding of the electronic structure by describing atomic orbitals using a set of four quantum numbers. The quantum numbers n, l, mₗ and ms and their associated energy states, are fundamental for describing the behavior and arrangement of electrons in the hydrogen atom.
In this lecture, students will be able to describe s and p orbitals in terms of their shape, orientation, and energy.
In this lecture, students will be able to describe d orbitals in terms of their shape, orientation, and energy.
In this lecture, students will be able to describe f orbitals in terms of their shape, orientation, and energy.
In this lecture, students will be able to identify, represent, and calculate the total number of electrons in a shell and a subshell
In this lecture, students will be able to describe the energy levels of the hydrogen atom and many-electron atoms, and explain the origin of non-degeneracy in many-electron atoms.
In this course, we present a systematic introduction to the fundamental principles of quantum mechanics that form the basis of modern atomic theory. The course begins with the Heisenberg uncertainty principle, which establishes the intrinsic limits on simultaneously determining the position and momentum of an electron, emphasizing the departure from classical descriptions of particle motion. This is followed by the Schrödinger equation, the central equation of quantum mechanics, which provides a mathematical framework for describing the wave-like behavior of electrons in atoms. By solving the Schrödinger equation for atomic systems, students learn how quantized energy levels arise and how these solutions lead to four quantum numbers—principal, angular momentum, magnetic, and spin—that uniquely describe an electron’s energy, orbital shape, spatial orientation, and intrinsic spin.
The next chapter is devoted to atomic orbitals, focusing on both their geometric shapes and their relative energy levels. The characteristics and graphical representations of the s, p, d, and f orbitals are examined in detail, highlighting differences in symmetry and electron density distribution. Orbital energies are first analyzed for the hydrogen atom, where orbitals sharing the same principal quantum number are degenerate. The discussion is then extended to many-electron atoms, where electron–electron repulsion and shielding effects break this degeneracy, leading to the experimentally observed ordering of orbital energies and providing a foundation for understanding atomic structure and periodic trends.