
Explore polar coordinates by linking Cartesian x,y and polar r, theta via x = r cos theta, and y = r sin theta, with r = sqrt(x^2+y^2) and related derivatives.
Explore first order partial derivatives by treating other variables as constants, and learn the standard notation for partial derivatives with practical examples involving r, theta, sine and cosine terms.
calculate a mixed second-order partial derivative with respect to r and theta. use the product rule and treat constants to obtain an expression involving cos theta and sin theta.
Explore mixed second-order partial derivatives, focusing on derivatives with respect to multiple variables, pattern recognition for product rules, and evaluating trig derivatives like cos and sin with respect to theta.
Explore derivatives of cosine and sine using prime and partial notation across single- and multi-variable functions. See mixed partial derivative concepts with cosine squared and sine relations.
Explore a general result in thermodynamics by examining how mixed second partial derivatives are equal, shown through calculating partial derivatives with respect to theta and using cosine and sine relationships.
Learn how differential forms serve as a key mathematical tool in thermodynamics, distinguishing exact differentials from non-exact ones and identifying potential functions for multi-variable systems.
Evaluate differential forms for exactness by verifying ∂A/∂y = ∂B/∂x in two variables. Clarify notations: use d for derivatives and ∂ for partial derivatives, and distinguish exact from inexact forms.
Determine when a differential form is exact by checking ∂M/∂y = ∂N/∂x, and relate to total differential dF = M dx + N dy for functions of x and y.
Explore when a two-variable differential is exact and find the potential function f(x,y) using the total differential and partials, where f_x = y sin x and f_y = -cos x.
Learn to integrate a function of two variables in x while holding y constant, yielding F(x,y) = - y cos x + C(y), where integration constant may depend on y.
Examine a two-variable function f(x,y) and verify the constant is independent of y via partial derivatives and exactness, yielding f(x,y) = a − y cos x + c.
Demonstrate that entropy S is a state function of temperature and volume by constructing ds as an exact differential and integrating to S(T,V) with a constant.
Identify the state function in thermodynamics by treating s as an exact differential; verify conditions with partial derivatives to show dS forms a state function.
Compute the line integrals of work along the path A-C-B in the PV plane, relating W1 and W2. Show the PV differentials are exact with a positive constant.
Demonstrate evaluating a simple path integral from a to b, with constant pressure and PV work terms, showing how PDV and DV contributions combine in a particle-like case.
Compute the path integral of work along the piecewise path a→c→b, showing constant-volume segments contribute zero, and express the total work as minus P dV plus PV differences.
Demonstrate that the line integral w1 is path-independent as an exact differential, and that w2 is inexact, depending on the chosen path from a to b.
Examine exact differential forms and verify path independence by comparing partial derivatives; show w1 is exact with an endpoint-dependent integral, while w2 is inexact and path dependent.
Revisits exact differential forms, applies partial derivatives and exactness tests to identify when a differential is exact, and sets up the next topic.
Explore exact differential forms in thermodynamics, using partial derivatives with respect to P and V to integrate W4, even without full knowledge of W3.
This course is reserved for people who have never had a thermodynamics course, or who have never had an advanced course on differential calculus. Anyone can use it just needs a HighSchool Diploma level, this course is presented as a direct application where every detail is explained. Each quiz contains a detailed answer with explanation.
Before any thermodynamics course we need mathematical tools like :
In this course we present all this concept for beginner
Our method is detailed the calculation from A to Z .
Content and Overview
About 4 hours of classes using a white board as a real university course for total immersion.
We start with a recall about the polar coordinates followed directly by a quiz with detailed correction, after this we attack the notion of partial derivative of a function of several variables, here, for simplicity we will only see the functions of two variables, but to understand for two variables is to understand automatically for several variables, after that, we will see the mixed derivative.
During our course we will see quite a recall on some rules of derivation already seen in high school.
At the end of section 1 we will see an interesting property in thermodynamics, a general result.
In the second part of this course we shall attack the notion of differential forms, very important concept in thermodynamics, we shall see especially the notion of an exact differential form of a function, since all the functions in thermodynamics their differential is exact.
In the third part we will see the notion of "state function", because all the thermodynamic functions are state functions.
Finally part 4 is a great application of that has been seen previously, it is like a summary, but in this part we will also calculate very simple path integrals for beginners, just to see that there exist such integrals, wich may depend on the path taken.
And at the end we will see an example of an integrating factor, which in fact multiplied by a differential form will allow to integrate, hence its name.