
Description of all what we will cover in this class
What is a Base? What means pH? What is a redox Reaction? We will discuss what you need to know in order to take this class.
An overview of all steps needed to make cathode materials and get them in a battery
about books and publications...
You will learn the main component of a LiB battery
We will have a look to the most common cathode materials: NMC, LCO, NCA...
A short description on how a LiB works.
Overview on Books, Websites and Literature about Batteries in General
Short Recap on the chapter construction on the flowsheet.
Short overview on Terminology: what is a rock? A mineral? An Ore? Gangue Rock?
Explore how nickel and cobalt occur in sulfide and laterite ores, in recycling, and as byproducts, and identify pentlandite, garnierite, cobaltite, and processing routes.
Presentation of the general goals followed by an overview of crushing and screening processes.
An rudimentary examples of a flowsheet
Explore how a hydrocyclone in a water slurry uses high-speed inlet flow and rotational movement to create centrifugal force, separating larger, heavier particles from lighter ones that escape the vortex.
Apply froth flotation to separate sulfide ores, concentrating nickel and cobalt minerals like pentlandite while discarding gangue rocks; use flotation agents and pH changes to refine the concentrate.
Explore essential resources on crushing, screening, and froth flotation for minerals, including books, websites, and videos that illustrate crushers, particle size reduction, and flotation reagents.
Overview of the Chapter Pyrometallurgy along with Books used
Overview of the Pyrometallurgical Process with the different steps: Roasting, Smelting and Converting
More details in the three pyrometallurgical steps: Roasting, Smelting and Converting
Further Reading Section
Recap: Overview of the Chapter Hydrometalurgy
What is leaching, how does it work and how can it be used to leach Nickel-Matte.
Overview of the different Refining Steps, which will be presented in the next lectures
Overview how Ion Exchange can be used to remove impurity or clean up Co- and Nickel-containing solutions
Cementation is also a form of precipitation, but using spontaneous redox-reaction.
Describe electrowinning as a redox process where current drives copper ions to the cathode, depositing metallic copper while water splitting occurs at the anode, enabling impurity removal or metal recovery.
Overview of the Principle of Solvent Extraction and how it works
At the end of the extraction process, several posttreatment steps are needed: Scrubbing, washing, stripping
More details on Solvent Extraction: we will see an examples and have a look to coordinating agents
Explore essential reference books on hydrometallurgy and solvent extraction, covering leaching, electrowinning, and nickel, cobalt, and platinum group metals topics from Crundwell, Havlik, Habashi, and Ullmann.
Master spray pyrolysis by nebulizing metal solutions into droplets, forming metal salts that oxidize into nickel or cobalt oxide particles and collect as oxide powder using carrier gas.
Routes if you want to avoid Pyrometallurgy Steps
Explore lithium demand from batteries to other applications, such as ceramics, greases, polymers, glass, and air-treatment; it is not highly scarce, but diluted and sourced mainly from brines and ores.
Ways to transforming Lithium Carbonate to Lithium Hydroxide
Chapter Overview and Learning Goals
Explore the preparation of the precursor material for NMC cathodes, using coprecipitation to form atomic-level mixed metal hydroxide or carbonate particles from CoSO4, NiSO4, and MnSO4.
Learn how a coprecipitation reactor forms nickel manganese cobalt precursors for NMC811, using ammonium hydroxide complexes, pH and temperature control, and subsequent filtering and washing.
After precipitation, perform filtration with belt filters or centrifuges, then wash, dry, and sieve to produce precursor powder for the cathode.
Explore cathode refining through surface coatings: oxide, fluoride, oxyfluoride, and carbon to protect particles, improve electron and ion transport, and reduce HF-driven side reactions and metal leaching, boosting stability.
finally we have finished the cathode material...
Alternatives to Coprecipitation Routes: Sol-Gel and Spray Drying
Discover how to mix and coat cathode material on current collector, dry and calendate it, and wining and stacking with the anode and separator before electrolyte fill and first charge.
Identify the electrode as the anode and cathode. Show how a single unit becomes a cell, and how several cells form a module and a battery pack.
Mix active cathode material with carbon black, binder, and additives to form a slurry, then coat on the current collector with a doctor blade.
Pouchell Making at Helmholtz Institute Ulm
Explore winding and stacking in lithium-ion battery manufacturing, detailing how cathode, separator, and anode layers are rolled for cylindrical or prismatic cells while preventing contact.
Fill the electrolyte under water-free conditions using lithium hexafluorophosphate in ethyl carbonate and dimethyl carbonate, in glovebox or dryroom, to prevent hydrofluoric acid formation and cathode aging.
Explore the final assembly of lithium-ion batteries, assembling cells into modules and packs, adding cooling, contacts, electronics, sealing, testing, certification, and recycling considerations from mine to battery.
Chapter overview and recap on how much metals are inside a battery
Trace the battery life cycle from mining and refining to cathode material, cell, and pack. Show end-of-life steps—collection, dismantling, furnace metal extraction, and second-life use—toward greater recycling.
Description of the lifecycle of a battery
Explore mechanical pretreatment and hydrometallurgical and pyrometallurgical routes for recycling spent lithium-ion batteries, including separation techniques and a car battery dismantling flow sheet.
Explore lithium-ion battery recycling, covering life-cycle concepts and methods like hydrometallurgy, pyrometallurgy, and bio-hydrometallurgy, with recommended readings such as recycling of spent lithium-ion batteries and LithoRec Way.
This class focuses on cathode materials used in today's lithium-ion batteries (LiB).
Today's cathode materials typically contain lithium, nickel, and cobalt compounds. In this class, you will explore how to find the resources to make the cathode materials in the first place and all the steps to the finished battery from scratch.
We will cover the mineral sources and mining stages of lithium, cobalt, and nickel. All the approaches to extract these metals from the ores, including details on pyrometallurgy and hydrometallurgy. We will study the processing of the final cathode material. And how these materials are assembled into a battery. We will also cover recycling options for spent lithium ion batteries.
The purpose of this course is NOT to teach you about electrochemistry, nor about battery performance or the pros and cons of specific battery types.
The specific focus of this course will be on nickel, cobalt and lithium extractive metallurgy and the synthesis and assembly of common cathode materials such as LCO, NMC and NCA.
Learn how LiB works and what it contains.
Study the mining and processing operations: the ores, the crushing and screening operations, the froth flotation.
Become familiar with the extractive metallurgy of cobalt and nickel.
Find out how to perform leaching, electrowinning, or solvent extraction to obtain pure nickel and cobalt salts.
You'll also cover a complete section on lithium refining: learn where to find lithium resources. How to process brines and lithium ores.
Learn how to prepare the final cathode materials: including coprecipitation, lithiation, calcination, and cathode refining.
Assembling into a battery: electrode preparation, assembly with anode and separator, winding, electrolyte filling, and initial charging.
Recycle batteries: Explore battery life cycle, recycling flowsheet, treatment of small and large batteries.
Get inspired to keep learning with the large amount of literature, websites and books I have picked out for you.
Familiarize yourself with making cathode materials for LiB hassle-free! This class is very comprehensive: I have about 10 years of battery experience (ass well in academia as in industry) and a total of 20 years of chemistry research under my belt. Therefore, this course will be your reliable guide for cathode material preparation.