
Explore the fundamentals of corrosion, reference electrodes, and the Nernst equation, then cover polarization, Faraday’s law, and cathodic protection design for galvanic, sacrificial, and impressed current systems.
Explore the fundamentals of corrosion, including electrochemical and chemical reactions, and learn how anode, cathode, and electrolyte drive degradation and the main corrosion forms.
Explore how electrode potential acts as the driving force in corrosion, forming galvanic cells between anode and cathode in electrolytes. Learn about reference electrodes and field measurements.
Explore reference electrodes such as saturated calomel and silver chloride, potentials versus standard hydrogen electrode, and how temperature and concentration corrections use Nernst equation to assess corrosion via Faraday's law.
The Pourbaix diagram illustrates stability boundaries for water and iron species, showing hydrogen and oxygen lines and regions of corrosion, passivation, and immunity.
Explore polarization in cathodic protection, including activation and concentration polarization from kinetics and thermodynamics, open circuit potentials, and the event diagram of current versus potential.
Explore how cathode and anode polarization vary with current and voltage. Learn how reactant concentration, dissolved oxygen, hydrogen ions, temperature, agitation, surface area, coating integrity, and currents drive charge transfer.
Analyze how increasing polarization at the anode and cathode influences driving voltage, current, and corrosion in a cathodic protection system, considering circuit resistance, time, and EMF effects.
Apply cathodic protection to convert the protected metal to a cathode. Inject current to polarize toward the anode's open circuit potential, reducing corrosion.
This lecture explains cathodic protection criteria, defining -850 mv vs copper sulfate as the potential criterion and 100 mv polarization shift, measurement methods, and temperature and sulfate-reducing bacteria adjustments.
Describe galvanic sacrificial anode systems and semi-inert anodes with a power supply, including core components and how a sufficient potential difference protects steel structures.
Explore galvanic (sacrificial) anode systems, including anode backfill in soil and water, alloyed electrodes, wiring, to provide ionically conductive paths, minimize resistance, and protect offshore structures and underground storage tanks.
Explore the impressed current cathodic protection system, detailing anode types, carbon backfill, power supplies, wiring, and the contrasts with galvanic anodes to prevent corrosion.
Learn cathodic protection design fundamentals, choosing galvanic or current systems and calculating current requirements, ground-bed layout, and power needs from pipeline and environmental factors.
Explore calculating cathodic protection current for coated and bare steel, using coating percentage, environment, and field tests, including minimum voltage drop, coating resistance, and polarization methods.
Calculate cathodic protection current and circuit resistance by analyzing structure and cable resistances, anode and cathode potentials, and vertical or horizontal anode layouts with backfill.
Calculate cathodic protection system capacity and lifetime by linking electrochemical capacity to current requirements, anode weight, and efficiency factors; apply galvanic and improvised current design methods with example calculations.
Corrosion is one of the most important problems encountered by the owners and operators of underground, offshore, submerged and other metallic structures exposed to an electrolyte. If corrosion is not controlled, it can lead to large costs in repairs or facility replacement. Even greater costs can be incurred from environmental damage, injuries and fatalities.
Corrosion control personnel must have a good basic understanding of corrosion mechanisms. They also need to know the various conditions under which corrosion can occur on underground facilities. In this course, we will focus on the control of metallic corrosion by applying cathodic protection. This course was developed for cathodic protection field technicians, although this knowledge is also needed by corrosion engineering personnel. Cathodic protection (CP) is a corrosion-control technology that involves making a metal surface the cathodic side of an electrochemical cell. Connecting the metal to be protected with a more readily corroded metal to act as the anode of the electrochemical cell is the easiest way to apply CP. In theory, cathodic protection can be used to protect any metallic structure in contact with a bulk electrolyte. However, it is most commonly used to protect steel structures buried in soil or submerged in water in practice. Cathodic protection systems protect a variety of metallic structures in various situations. The most prevalent are water and fuel pipelines, storage tanks, ships and boats, offshore oil platforms, oil well casings, and other applications. This chapter will go through the fundamental principles of cathodic protection and current advancements in the field.